![]() The electronic configuration of 4f14 5d10 corresponds to the element Hg2+, because the two-electron is removed from Hg. ![]() The electronic configuration of 4f14 5d106s2 corresponds to the element Hg.The electronic configuration of 4f14 5d106s26p2 corresponds to the element Lead( Pb).The electronic configuration of 4f14 5d86s2 corresponds to the element Platinum.The repulsion between the electrons in the 3d orbital is lower than the repulsion between the electrons in the 4s orbital which is wrong.This statement is correct but this is not the correct explanation for the unusual electronic configuration shown by the Cu atom. The complex cross-terms in quantum mechanics must be considered when we have a large number of electrons present.The d orbitals have low energy than the 4s orbital so they fill first, but here the half-filled and completely filled subshells are more stable and this is an exceptional case.Half-filled and completely filled subshells are observed to be more stable and have lower energy.The ground state electronic configuration of copper 4s13d10 instead of 4s23d9 because half-filled and completely filled orbitals are more stable and of lower energy. Educational Research: Competencies for Analysis and Applications (Gay L.The Methodology of the Social Sciences (Max Weber).Forecasting, Time Series, and Regression (Richard T.Business Law: Text and Cases (Kenneth W.Brunner and Suddarth's Textbook of Medical-Surgical Nursing (Janice L.Interpersonal Communication (Kory Floyd).Bursten Catherine Murphy Patrick Woodward) Chemistry: The Central Science (Theodore E.Give Me Liberty!: an American History (Eric Foner).Civilization and its Discontents (Sigmund Freud).Biological Science (Freeman Scott Quillin Kim Allison Lizabeth).Principles of Environmental Science (William P.Techniques DE Separation ET Analyse EN Biochimi 1.SEC-502-RS-Dispositions Self-Assessment Survey T3 (1).School-Plan - School Plan of San Juan Integrated School.I am doing my essay on the Ted Talk titaled How One Photo Captured a Humanitie Crisis https.Leadership class, week 3 executive summary.The tenpoint plan of the new world order-1.MCQs Leadership & Management in Nursing-1.1-2 Module One Activity Project topic exploration.Ch 2 A Closer Look Differences Among the Nutrition Standard & Guidelines & When to Use Them.Time Value of Money Practice Problems and Solutions.C228 Task 2 Cindy - Bentonville - Passed with no revisions.MMC2604 Chapter 1 Notesm - Media and Culture: Mass Communication in a Digital Age. ![]() Weight Mass Student - Answers for gizmo wieght and mass description.How Do Bacteria Become Resistant Answer Key.Chapter 15 Anxiety and Obsessive-Compulsive Disorders.Test bank - medical surgical nursing 10th edition ignatavicius -zo8ukx.Business Core Capstone: An Integrated Application (D083).Comparative Programming Languages (CS 4402).Operating Systems 2 (proctored course) (CS 3307).Principles Of Environmental Science (ENV 100).Advanced Anatomy & Physiology for Health Professions (NUR 4904).Professional Capstone Project (PSY-495).Professional Application in Service Learning I (LDR-461).Managing Organizations & Leading People (C200).Expanding Family and Community (Nurs 306). ![]()
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![]() ![]() The company won't disclose its sales numbers, but given the fact it's promoting the gag reviews on its social media accounts means the attention the reviews provide is clearly boosting the bottom line. ![]() 2 on the website's "mandolins and slicers" category. The gag comments were made online, but as this story in BusinessWeek points out, they're for a very real device that sells for $4.89 (U.S.) on and ranks No. ![]() The Hutzler 571, a yellow plastic banana slicer made by Canaan, Conn.-based Hutzler Manufacturing, sounds like a joke product conceived by Looney Tunes or Saturday Night Live. Paul Friedman, a 59-year-old dentist in New York City, says he's using Facebook less now than when he first signed on four years ago, but he's not sure if the site has “become less interesting or that I am just less interested in it,” he says."What can I say about the 571B Banana Slicer that hasn't already been said about the wheel, penicillin, or the iPhone? … this is one of the greatest inventions of all time." The retooling, which is already available to some people, is intended to get rid of the clutter that's been a complaint among Facebook users for some time. In early March, Facebook unveiled a big redesign to address some of its users' most pressing gripes. Might Facebook go the way of email? Boyd, who is 35 (and legally spells her name with no capitalization), recalls being a teenager and “thinking email is the best thing ever.”įew people share that sentiment these days. ![]() “People don't want to hang out with everybody they have ever met.” “We have never seen a social space that actually works for everybody,” says danah boyd, who studies youth culture, the Internet and social media as a senior researcher at Microsoft Research. That's a sign that Facebook's biggest asset may also be its biggest challenge. But she prefers using Facebook to communicate because everyone she knows is there. Viral TikTok roasts Galveston beach ‘aesthetic' and 'caca water'įernandez uses Facebook in the same way that people use email or the telephone.Apartments, condos and hotels would anchor new downtown development near River Walk.These 17 San Antonio restaurants closed for good in 2023.Man accused of having an affair shot, killed on San Antonio Southside.Magnolia Pancake Haus opens its newest location and more food news.Rudy Farias' neighbors question if he was really missing for 8 years.Former San Antonio sports anchor charged with murder in Corpus Christi.Though the Traverse City, Mich., high school senior doesn't look at her News Feed, the constant cascade of posts, photos and viral videos from her nearly 1,800 friends, she still uses Facebook's messaging feature to reach out to people she knows, such as a German foreign exchange student she met two years ago. Indeed, Fernandez hasn't abandoned Facebook. Facebook has more than 1 billion users around the world. The company, which depends on targeted advertising for most of the money it makes, booked revenue of $5.1 billion in 2012, up from $3.7 billion a year earlier.īut so far, for every person who has left permanently, several new people have joined up. If Facebook Inc.'s users leave, or even check in less frequently, its revenue growth would suffer. The Pew Research Center's Internet and American Life Project recently found that some 61 percent of Facebook users had taken a hiatus from the site for reasons that range from “too much gossip and drama” to “boredom.” Some respondents said there simply isn't enough time in their day for Facebook. If you had a Facebook you kind of fit in better, because other people had one,” says Rachel Fernandez, 18, who first signed on to the site four or five years ago.Īnd now? “Facebook got kind of boring,” she says.Ĭhatter about Facebook's demise never seems to die down, whether it's talk of “Facebook fatigue,” or grousing about how the social network lost its cool once grandma joined. “When I first got Facebook I literally thought it was the coolest thing to have. ![]() ![]() ![]() Vehicles will naturally have some problems and recalls occasionally. On top of the safety concerns, these also didn’t fare great for passenger friendliness. Not only will the occupants be chilly, but the windshield could have issues defrosting, posing a safety risk. The 2005-2007 Equinox models had several complaints regarding a malfunctioning heater. ![]() Take a look - some of the best used SUVs have gone mostly overlooked or forgotten. We looked into price, reliability, features, and more to create this list of the best used SUVs under $10k on the market today. With safety being one of the most significant factors in a new car purchase, the 2005-2007 Equinox model years are the ones to avoid if you’re searching for a family car. Although the back passenger seats performed well, the front passenger seats did not. Right from the jump, these model years performed poorly in the IIHS crash test in both the side and head restraints & seat categories, and they earned a mediocre to below-average rating. Equinox Models to Avoid: First-Generation 2005-2007 Problems:Īs a first-generation vehicle, the 2005-2007 models had their fair share of issues. It should be noted that none of these should be considered terrible vehicles, as every make and model has its pros and cons. It was, however, entering one of the most competitive segments of the market, the crowded small crossover SUV segment. Tell us what you’re looking for and we’ll send you a curated list of the best used Chevrolet listings in your area - no more scrolling through hundreds of listings looking for hidden gems.įor the 2005 model year, the Chevy Equinox was introduced as a successor for the famous Blazer and Tracker SUVs. The CoPilot app is the smartest way to buy a Chevrolet. GET A CURATED LIST OF THE BEST CHEVROLET LISTINGS It was developed to replace a few aging SUVs in the Chevy family and set itself apart from the Blazer by offering all-wheel drive instead of the Blazer’s rear-wheel drive. Does this new styling mean there are specific Equinox model years to avoid?īefore the Equinox’s inception, many other cars and SUVs used the unibody construction, but this was the first Chevy SUV to do so. This means the structure and body were built as one. It was a first, as all Chevy SUVs models were designed with body-on-frame construction, and the Equinox was the first to have the body and the frame be built as two independent entities in body-on-frame construction. The Equinox first debuted in showrooms back in 2005 and has seen pretty consistent success over the years as a popular crossover SUV. ![]() ![]() It's possible the MOB Games-created brand will similarly reach the stratosphere in the years ahead. Unsurprisingly, ongoing talk about what MOB Games has in store for Chapter 2 continues to ignite discourse comparing Poppy Playtime to Five Nights at Freddy's, another toy-centric horror phenomenon that managed to explode outside of the gaming sphere. Chapter 2 could see the property's influence elevated further, too, especially if Mommy Long Legs catches on like Huggy Wuggy before her. The terrifying iconography associated with Poppy Playtime has already become the stuff of legend. When developer and publisher MOB Games intends to share such details presently remains a mystery, as well. At the very least, fans can rest assured the sequel's launch remains on track for a 2022 rollout. A screenshot of the listing in question appears below:Īgain, it doesn't seem as though the above mentioned April release date for Poppy Playtime Chapter 2 is set in stone as of yet. This information could prove inaccurate, so it's best to take the SteamDB information with a grain of salt for the time being. The " Release Date" section near the top of the Poppy Playtime Chapter 2 page on SteamDB simply says, " Coming Soon." However, the " Store API Release Date" box at the bottom mentions April 29 as the due date. Related: Police Are Issuing Warnings About Poppy Playtime's Huggy WuggyĪs reported by Gamereactor, the SteamDB page for Poppy Playtime lists the release date of Chapter 2 as April 29. And recent developments suggest players will get to determine that much for themselves in the very near future. After Poppy Playtime's port to Android and iOS devices a few weeks ago, even more horror fans patiently await the forthcoming release of Chapter 2, which looks as though it will considerably increase the scare factor. ![]() ![]() It didn't take long for the horrific blue monster to become the stuff of nightmares given Poppy Playtime's meteoric rise in popularity throughout the last several months. ![]() ![]() ![]() Marvel, She-Hulk, Peter Parker, Spider-Man, Thor, White Tiger, Doctor Octopus, Kraven the Hunter, Shocker (Classic), The Presence This isn't just the most polished Lego Marvel game - it's probably the most polished Lego game to date, period.Drax, Gamora, Groot, Rocket Racoon, Star-LordĬaptain America (Pilot), Captain Marvel, Captain Marvel (No Mask), Ms. Lego Marvel Super Heroes 2 doesn't try to reinvent the wheel, but rather takes the parts that fans have loved about the Lego games, fine-tunes it all, and crams in more content until the final package is almost bursting at the seams. If you've played any Lego game in recent memory, you'll probably already have an idea of what to expect. And, unfortunately, there's still the rare awkward camera angle that can lead to an occasional frustration or two. There's the toy-on-toy combat and rampant environmental destruction that the games are known for. There are plenty of puzzles to solve, some basic and some more complex, requiring the use of certain characters' special skills and abilities. Of course, all the characters and trivia in the universe don't add up to much of anything if the game isn't actually fun to play. It's the little things like these, as well as the seemingly trivial details (such as Star-Lord whipping out his Walkman and jamming out to some classic rock), that make the game a true love letter to Marvel comic fans new and old. ![]() Even the most hardcore Marvel fan might be hard pressed to remember some of the more obscure characters, but thankfully, the game's character selection screen includes handy character cards that sum up not only characters' abilities, but their history in the Marvel Universe as well. Lego Marvel Super Heroes 2 is no different, with an epic original adventure starring a robust cast of characters pulled from nearly every corner of Marvel's deep history. Whenever Lego and Marvel join forces, it's always a collaboration on par with the greatest superhero team-ups and comic book crossover events. From Captain America to Gwenpool, Star-Lord to Forbush Man, Squirrel Girl to Rocket Racoon, it's every Marvel fan's dream come true, brought to you as only Lego can. and have more than just a little fun doing it. Heroes from every corner of the Marvel Universe join together in an epic display to bring down this cosmic threat. And that call is answered, in the far reaches of space, through pages of times past and the distant future, and even across the multiverse itself. The call goes out far and wide to those willing to rise up and stand together against Kang and his allies. When the world's greatest superheroes are unable to stand against Kang's power, it's time to find some unlikely reinforcements. When the time-traveling despot Kang the Conqueror arrives high above the earth, he launches an all-out assault as part of his latest scheme to rule the universe. In LEGO MARVEL SUPER HEROES 2, it's not just the fate of the world at stake, or even the universe all of time itself is at risk. SERIOUSLY THOUGH!! How is that too much violence. You hit someone they say "oof" and a cartoony heart dissapears. Heroes fight bad guys, it's not like this game is graphic with the violence. If you think this has too much violence for your kid then you shouldn't have even introduced any superhero in existence. People are also complaining there's too much violence but there really isn't. So Kang is actually one of my favorite characters in the game because, although he's the villain, he also serves as comedic relief. The plot is also very interesting, so you go through time with a variety of characters to stop Kang the Conquerer. If you are an MCU mega fan you will be pleased to see all kinds of easter eggs they've hidden in the game, which I am not going to spoil. The missions are super fun and there are all kinds of mini-missions in the game. One of my favorite aspects of this game is that it's a good sequel to the first, however, with that in mind, you don't actually need to complete the first version of this game. I'm really confused why this has consumerism in it when in reality, it doesn't. ![]() ![]() **If you don't have a food processor, a high speed blender MAY work for this. **Depending on how long you soaked the cashews, you may need to add a couple more tablespoons of almond milk until mixture is fully blended. Mixture should be creamy at this point - if there are still a few lumps, add the 2 tablespoons of almond milk and pulse again. Add soaked cashews, shredded coconut, coconut nectar, vanilla extract, and pulse for 5 minutes. Place in freezer, and start making the filling!ģ. Quickly wash out food processor, and reuse to make the filling. The crust layer should be pretty thin, but don't worry - it's super sweet and flavorful. ![]() ![]() Add crust to pyrex, firmly pressing onto the parchment paper. Line a 8x8 pyrex pan with parchment paper, and set aside.Ģ. In a food processor, add all crust ingredients and pulse for a few minutes, until sticky. 1 cup fresh or frozen raspberries (I've used frozen and it works great)ġ.2 tablespoons coconut nectar (You could sub honey or maple syrup, but it'll taste diff). ![]()
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